GOLDEN Colour Mixing Guide


Throughout history, painters and authors have recommended various palettes of colour. While some give insight to the painter's working style, others offer a simple palette for mixing, but typically limit colour possibilities. GOLDEN has created a palette of eight professional acrylic colours to provide you with the potential to mix the widest range of colours.

The Selection of Colours for Mixing

For this palette, the three mixing primaries are Hansa Yellow Medium, Quinacridone Magenta and Phthalo Blue (Green Shade). Our standard recommendation is Quinacridone Red, but we chose Quinacridone Magenta for mixing a broader range of violets and purples.

Naphthol Red Light helps balance the Quinacridone Magenta. Mixtures with Hansa Yellow Medium reveal a wider selection of intense reds and oranges. Mixtures with Phthalo Blue (Green Shade) allow deep reds and maroons.

Phthalo Green (Blue Shade) assists Phthalo Blue (Green Shade). Mixtures with Hansa Yellow Medium produce a great range of greens, particularly subtle yellow greens. This green also helps create a diverse range of earthtones.

Yellow Ochre, a natural earth colour, helps "warm" the colour mixtures and subdue the brightest colours.

Titanium White is an opaque white for mixing pastel tones. Zinc White is an extremely transparent white for subtle tinting and glazing.

The Qualities of Colour

To describe colour we need to understand three qualities: Hue, Chroma and Value.

Hue is another word for colour. It describes the actual colour of something. Red, Green and Blue are hues. A cucumber and a lime are both hues of green.

Chroma is also known as a saturation or intensity. It describes how brilliant or subdued the colour looks. For example, within the hue of yellow, a lemon has more chroma than a banana.

Value refers to a colour's lightness or darkness as compared to white or black. Yellow is lighter in value, or closer to white, than dark blue. Sometimes it is difficult to determine the value of middle toned colours like orange and green. We easily understand value when we look at the range of Neutral Grays on the Virtual colour Guide. Try squinting while looking at colours to determine their value. Squinting helps the eyes' black and white receptors make value determinations.
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The Qualities of Paint Colour

Pigments are the particles in paint revealing hue. Every pigment is classified into two basic categories based on chemical composition - Organic pigments and Inorganic pigments.

Organic Pigments
Organic pigments are formed from complex carbon chemistry and are synthetically derived in laboratories.

Most organic pigments offer high chroma, high tinting strength and exceptional transparency. A transparent organic pigment, like a small piece of stained glass, allows light to pass through practically undisturbed. This characteristic allows mixtures with relatively high brilliance and clarity. Our mixing set includes five colours made from organic pigments: Hansa Yellow Medium, Quinacridone Magenta, Phthalo Blue (Green Shade), Phthalo Green (Blue Shade) and Naphthol Red Light.

Inorganic Pigments
Inorganic pigments are not based on carbon chemistry, but instead are derived from natural minerals or ores. These materials are oxides, sulfides, or various slats of metallic elements. Examples include iron oxide, cadmium sulfides and titanium dioxides.

Most inorganic pigments offer relatively low chroma, low tinting strength and a moderate to high degree of opacity. (Zinc is the exception.) Using inorganics for blending colour yields mixtures with low chroma, but excellent opacity. Our mixing set includes three colours made from inorganic pigments: Titanium White, Zinc White and Yellow Ochre.
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Other Paint Colour Terms

In order to more fully understand how to mix acrylic colour we need to define other important attributes of paint colour including: Masstone, Undertone and Tinting Strength.

Masstone
The masstone, or body colour, is paint applied so it totally covers the surface. No other colours from below show through. For example when Phthalo Blue is thickly applied, the masstone appears black.

Undertone
The undertone of a colour is visible when we spread the colour very thinly over a white surface. This can be done by scraping the colour over a surface or by thinning the colours dramatically with acrylic medium or water. Certain colours, such as the Cadmiums and Cobalts, have similar masstones and undertones. With the transparent organic colours like the Quinacridones or Phthalos, the undertone can be quite different from what might be expected by looking at the masstone. These shifts in hue positions provide some of the incredible richness and magic to working with colour.

Undertone is important when using acrylic in a watercolour style, as the brilliance of watercolour comes from the white paper transmitting through the transparent layers of colour.

Tinting Strength
The final term we need to define before we explore the practical use of the colours is tinting strength. This is the ability of a colour to change the character of another colour. We determine this by adding the same amount of Titanium White to each colour and observing the resulting strength of the colour mixture. Weaker tinting colours create light pastel mixtures. Stronger tinting colours create darker mixtures.
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Colour Wheel and The Additive Primaries


The colour wheel provides structure to the discussion of colour and gives a reference point that allows us to draw useful conclusions about how colours interact. We start with Blue, Red and Green. In the natural world, these colours exist along the electromagnetic spectrum in a straight line, but we gain great insights into colour mixing by plotting these primaries on an equilateral triangle. We also plot the subtractive primaries, Cyan, Magenta and Yellow.

Natural white light contains all colours. When light hits a surface, its energy is absorbed, reflected or bent. A surface painted Black absorbs almost all the light energy that hits the surface. A surface painted White reflects all the light energy back from the surface. A surface painted Yellow absorbs Blue and reflects the Red and Green within the white light. colours absorb certain wavelengths of energy and reflect other light energies.

Unfortunately, pigments are not perfect primaries. They do not create a perfect Blue, Red or Green. They do not create Magenta, Cyan or Yellow. We only use a colour wheel to align colours and we use practical experience to truly understand how they mix with one another.

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The Artist's Colour Wheel and The Mixing Primaries

Artists are familiar with colour wheels showing Red, Yellow and Blue as primaries and Purple, Orange and Green as the secondaries. Secondaries result from the mixture of two primaries, i.e. Red and Yellow make Orange.

This colour wheel shifts colours around dramatically. It usually forces colour choices such as Cadmium Red, Cadmium Yellow and Ultramarine Blue, all of which use opaque inorganic pigments. These colours, although beautiful in their own right, severely limit colour mixing possibilities. The resulting mixtures show lower values and chromas than mixtures with organic pigments.
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Mixing Complementary Colours

We filled the colour wheel with our colour names so we can use it to develop an understanding of mixing possibilities. Mixing from opposite sides of the colour wheel will yield black or gray. This is called mixing complements. For example, we see that Phthalo Green and Naphthol Red Light are almost directly opposite one another. The mixing of these two will yield a simple black. For this reason, the mixing set does not include black.

Adding a colour's complement reduces the chroma of the mixture. For example, mixing a small amount of Phthalo Green into Naphthol Red Light reduces its intensity, however, it also changes the value of the colour. To avoid reducing the chroma of the mixture, use the Neutral Gray of the same value as the colour you are trying to mix, or mix a gray from the black produced with your Green and Red mixture with Zinc or Titanium White.



Varying Tinting Strength of Colours

Before we explore the blending possibilities and colour relationships, we need to describe the colours in the mixing set. The pigment loads are not balanced as with "student grade" colours. With professional "artist grade" colours, the high tinting colours are much more powerful than lower tinting colours. The highest tinting colours are Phthalo Blue and Phthalo Green. Next are Naphthol Red Light and Quinacridone Magenta. Hansa Yellow Medium has very little tinting strength.
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Relative Tinting Strength of Colours

To mix the colours, use this table as a guide. For example, to mix Turquois, mix equal parts of Phthalo Blue and Phthalo Green. To mix Bright Green, mix 1 part Phthalo Green with 9 parts Hansa Yellow Medium.

Tint Strength of Hansa Yellow Medium: In order to balance the much stronger tint strength of Phthalo pigments, try Hansa Yellow Opaque. It provides greater opacity; however, some chroma or intensity may be lost. To achieve some of the more transparent colours, add transparent Gel or Polymer Medium

Achieving Opacity with White

If you have ever been to a paint store and had colour mixed, you have seen the process of adding white. Each house paint colour, to develop opacity, is mixed with white. Most brands produce three different mixing whites; one very strong white for pastel hues, one middle strength white for middle colour values and one fairly weak white for deeper tones of colour.

Adding Titanium White to any of your colours will increase the coverage of your colour. This is especially true for the more transparent colours. It is also a general rule that the lighter the original value of a colour, the less dramatic the value shift when you add Titanium White. Adding Zinc White to transparent colours will not dramatically increase your opacity. It can be used to create subtle, tinted glazes. Keep in mind the resulting mixes will not provide good coverage.

If you choose to increase opacity, but do not want to change your colour value, then you must first mix a gray of the same colour value. As before, this will reduce your chroma, but will allow you to maintain your balance of light to dark while increasing your opacity.


Mixing Earth Colours

A good deal of painting requires the use of the earth colour palette. With high chroma colours, it seems almost impossible to mix colours like Burnt Sienna, Red Oxide or Raw Umber. Mixing medium greens through lime greens with orange-reds through orange-yellows offers an incredible array of earth colours. When you mix organic pigments, you maintain excellent clarity of colour.


Mixing Muted Colours


The colour blends achievable with the five mixing primaries, plus the two whites, is enormous. Yet, you may need to reduce the intensity of the colour for a more subtle quality. Yellow Ochre offers a warming of colours with a subdued glow. Used with Titanium White to tint colours, Yellow Ochre furnishes an opaque alternative to the bright white used to create the pastel range. Used with Zinc White, Yellow Ochre is transparent enough to create a glazing mixture, or deeper warmer tones within the more brilliant colours. Some artists suggest using Yellow Ochre instead of Hansa Yellow Medium to create a different palette of colours.
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Using Artist Acrylic Products

A glass palette offers a great surface for working with acrylic colours. Its smooth, nonporous surface makes mixing colours quite easy.
Acrylics dry by the process of evaporation. As the water releases from the paint, the acrylic polymer spheres come in greater contact with one another and eventually fuse to form a continuous film. To extend the working time of acrylic, you can add GOLDEN Retarder to the paint. GOLDEN Acrylic Glazing Liquid can be added to create glazes and will also keep the paint wet longer. To keep the palette fresh, we recommend lightly misting the colours on the palette with water every few minutes. A plant mister works well.

The acrylic used with all professional artist colours is an emulsion product. It is created by chaining together hundreds of thousands of acrylic molecules (monomers) within a water base. The process to make acrylic compatible with water requires a surfactant. A surfactant acts like a bridge allowing water and acrylic to work together.

This procedure of mixing acrylic with water creates a milky emulsion. While you are working with the paint, the acrylic emulsion is quite white. The wet emulsion "tints" the colour; however, when the water evaporates, the acrylic shows its exceptional clarity. This causes a large shift in value in very transparent colours such as Phthalo Blue. The shift in value is not noticeable in colours with light values such as Hansa Yellow Medium so, be aware of the possible shifts in value of acrylic colours. It can be disappointing to mix a colour exactly the way you want, and to have it dry to a much deeper colour. It is helpful to lay down a little of your transparent colour and let it dry to see if it is still the colour you desire. Another way to compensate for this value shift is to add a small amount of Zinc White to the colour. To achieve glazes (very thin, transparent films), add Polymer Medium (Gloss) to the colour. To reduce gloss, add Matte Medium.

GOLDEN produces over 20 Gel Mediums to create a tremendous range of textures, finishes and working properties for acrylic paint. Because of their unusual strength, most colours can be diluted substantially with Gels or Mediums and still retain much of their colour strength.

Acrylics clean with soap and water. Keep tools wet to assist cleaning. If paints dry on the palette, simply run a wet sponge over the surface and wait about 1 minute. The acrylic will easily peel off. Avoid getting paint on clothing. It will hold quite well!
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